Ceramic Microstructures: Control at the Atomic Level

Front Cover
Antoni P. Tomsia, Andreas M. Glaeser
Springer Science & Business Media, Apr 30, 1998 - Technology & Engineering - 854 pages
This volume, titled Proceedings of the International Materials Symposium on Ce ramic Microstructures: Control at the Atomic Level summarizes the progress that has been achieved during the past decade in understanding and controlling microstructures in ceram ics. A particular emphasis of the symposium, and therefore of this volume, is advances in the characterization, understanding, and control of micro structures at the atomic or near-atomic level. This symposium is the fourth in a series of meetings, held every ten years, devoted to ceramic microstructures. The inaugural meeting took place in 1966, and focussed on the analysis, significance, and production of microstructure; the symposium emphasized the need for, and importance of characterization in achieving a more complete understanding of the physical and chemical characteristics of ceramics. A consensus emerged at that meeting on the critical importance of characterization in achieving a more complete understanding of ceramic properties. That point of view became widely accepted in the ensuing decade. The second meeting took place in 1976 at a time of world-wide energy shortages and thus emphasized energy-related applications of ceramics, and more specifically, microstructure-property relationships of those materials. The third meeting, held in 1986, was devoted to the role that interfaces played both during processing, and in influencing the ultimate properties of single and polyphase ceramics, and ceramic-metal systems.
 

Contents

Structure and Composition of Interfaces in Ceramics and Ceramic Composites
1
Making the Connection between Atomistic Modelling of Interfaces and Real Materials
13
Local Chemical Bonding at Grain Boundary of Si₃N₄ Ceramics
23
Design and Life Prediction Issues for HighTemperature Engineering Ceramics and Their Composites
35
Wetting and Work of Adhesion in OxideMetal Systems
65
Interface Materials for Oxide Composites
83
Ceramic Grain Boundaries and Interfaces
95
A Model System
107
Multiphase Ceramics from CombustionDerived Powders
463
Precise Temperature Thermal Gradient and Densification Determination in a ProportionalPower Microwave Furnace
471
State and Structure of Free Carbon in Dense SiC Developed by Smart Plasma Sintering
487
Colloidal Stability in Complex Fluids
495
High Temperature Colloidal Processing for GlassMetal and GlassCeramic FGMs
503
Multicomponent Oxide Coatings Via SolGel Process
513
Modeling the Structure of Glasses and Ceramic Grain Boundaries An Interstitial Approach
527
Interactions between AL₂O₃ Substrate and Glass Melts
535

The TEM Approach to HighTemperature Microstructures
115
GrainBoundary Films in a Silicon Nitride Ceramic at High Temperatures
123
Microstructure and Intergranular Phase Distribution in Bi₂O₃Doped ZnO
131
Thermodynamic Calculations and Model Experiments in the System TitaniaSilica
149
Atomic Structure of the 𝚺₅ 210001 Symmetric Tilt Grain Boundary in Yttrium Aluminum Garnet
161
Synthesis and Microstructure of Mullite Fibers Grown from Deeply Undercooled Melts
169
The CubictoHexagonal Transformation to Toughen SiC
177
A Combination of Surface Electron Spectroscopies and Transmission Electron Microscopies
191
Nanometer Level Characterization of Rapidly Densified Ceramics and GlassSemiconductor Composites
199
Accomodation of Volume Changes During DiffusionControlled Metal Precipitation Inside an Oxide Matrix
209
Control of the Microstructure of Polycrystalline Diamond and Related Materials via an Enhanced CVD Process
221
New Opportunities for Studies of Surfaces and Grain Boundaries
229
Effect of Packing Structure of Powder Particles in a Ceramic Green Body on Microstructure Development During Densification
239
Influences of Interparticle Stresses on IntermediateStage Densification and Grain Growth
247
Logical Analysis of Phenomenological Experimental Data
255
Sintering Behavior Microstructure and Properties of Fine Silicon Nitride Ceramics
263
Simulation of Anisotropic Grain Growth by Ostwald Ripening
277
Mullitization Behavior of Alpha AluminaSilica Microcomposite Powders
285
Processing of Textured Ceramics by Templated Grain Growth
303
Characterization of Second Phases in Translucent Alumina by Analytical Transmission Electron Microscopy
311
Origin and Control of Abnormal Grain Growth in Alumina
323
The Origin and Growth Kinetics of PlateLike Abnormal Grains in Liquid Phase Sintered Barium Titanate
331
Microstructural Control of Zinc Oxide Varistor Ceramics
339
Chemistry Wetting Adhesion and Oxygen Activity
349
CeramicMetal Reactions and Microstructures in Ceramic Joints
359
Joining Technology for CeramicMetal Composite Structures
369
Microanalysis of Buried MetalCeramic Interfaces Using Neutron Reflection
377
Recent Progress in Surface Activated Bonding
385
CeramicMetal Interfaces in Electronic CeramicsInterface between AIN Ceramics and Conductors
391
Densification of Tungsten Conductors in Cofired Aluminum Nitride Multilayer Substrates by the Addition of Manganese Oxide
399
Wettability of CuBased Alloys on Alumina and Joining of Alumina with Microdesigned NickelChromium Alloy Interlayer
407
Interface Nanostructure of Brazed Silicon Nitride
415
The Impact of Interfave Nonstoichiometry on GasSolid Kinetics
421
Reactions at Nanometric SolidLiquid Interfaces Influenced by Low Frequency Electromagnetic Fields and Microstructure Development of the Precipi...
429
Growth of Inorganic Crystals on the Surfaces of TwoDimensionally Assembled Organic Molecules
437
Reactive Coatings on Ceramic Substrates
447
Bioactive Coatings on Ti and Ti6Al4V Alloys for Medical Applications
543
Characterization of AluminaSilicon Carbide Ceramic Nanocomposites
551
Composite Powder Synthesis
559
Synthesis and Characterization of Ceramic Powders by Dual Irradiation of Co₂ and Excimer Lasers
567
Ionic Transport to Produce Diverse Morphologies in MgAl₂O₄ Formations Started from Powders of Varied Physical Nature
577
Microstructure Evolution During Oxidation of MgOSiC Composites
589
Synthesis Tailored Microstructures and Colossal Magnetoresistance in Oxide Thin Films
597
Magnetic and Interface Characterization of rfSputter Deposited Multilayered and Granular FeAIN Films
605
NanoSized Oxide Composite Powders Bulk Materials and Superplastic Behavior at Room Temperature
613
Electron Beam Control of Alumina Nanostructure and Al Bonding
623
Microstructure and Properties of SiCSiC and SiCIIIV Nitride Thin Film Heterostructural Assemblies
629
Correlating Simulation Defect Energy Calculations with HREM Images of Planar Defects in Electroceramics
637
Microstructural Studies of Strontium Titanate Dielectric Ceramics
645
Electrical and Optical Properties at the Interfaces of nBaTiO₃pSi
653
Bulk and Thin Film Properties of PbLa TiO₃ Ferroelectrics
659
Preparation and Properties of PZTPbTiO₃ Ceramic Composite
669
Growth of Oriented SnO₂ Thin Films from Organotin Compounds on Glass Substrates by Spray Pyrolysis
679
The Energy Barrier at the Interface of ZnO Contact
687
Fiber Coating Design Parameters for Ceramic Composites as Implied by Considerations of Debond Crack Roughness
695
Interfacial Design and Properties of Layered BN+C Coated Nicalon FiberReinforces GlassCeramic Matrix Composites
705
Stability of Carbon Interphases and Their Effect on the Deformation of Fiber Reinforced Ceramic Matrix Composites
713
Thermal Stability of Nextel 720 Alumino Silicate Fibers
721
Textured Calcium Hexaluminate FiberMatrix Interphase for CeramicMatrix Composites
731
Microstructure of the Particulate Composites in the Y TZPWC System
741
Reaction Mechanisms and Microstructures of CeramicMetal Composites Made by Reactive Metal Penetration
749
Eutectic Structures that Mimic Porous Human Bone
761
Mullite A Modern Ceramic Material
771
Influence of Different Rare Earth Elements
779
Microstructural Evaluation of Deformation Mechanisms in Silicon Nitride Ceramics
787
Microstructurally Induced Internal Stresses in the Silicon Nitride Layered Composites
795
Characterization of Microstructure and Crack Propagation in Alumina Using Orientation Imaging Microscopy OIM
803
Grain Boundary Chemistry and Creep Resistance of Alumina
815
The Role of Microstructure and Chemistry
823
Effect of Microstructure and Internal Stress on Mechanical Properties of WCCo Doped Al₂O₃TiCNi FGMs
833
Index
843
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